The vapor pressure of a substance is measured over a range of temperatures. A plot of the natural log of the vapor pressure versus the inverse of the temperature (in Kelvin) produces a straight line with a slope of -3.46 * 10 3 K. Find the enthalpy of vaporization of the substance.

Respuesta :

Answer:

28.7664 kJ /mol

Explanation:

The expression for Clausius-Clapeyron Equation is shown below as:

[tex]\ln P = \dfrac{-\Delta{H_{vap}}}{RT} + c [/tex]

Where,

P is the vapor pressure

ΔHvap  is the Enthalpy of Vaporization

R is the gas constant (8.314×10⁻³ kJ /mol K)

c is the constant.

The graph of ln P and 1/T gives a slope of - ΔHvap/ R and intercept of c.

Given :

Slope = -3.46×10³ K

So,

- ΔHvap/ R = -3.46×10³ K

ΔHvap = 3.46×10³ K × 8.314×10⁻³ kJ /mol K = 28.7664 kJ /mol

Based on the data provided, the enthalpy of vaporization of the substance is 28.7664 kJ /mol.

What enthalpy of vaporization?

The enthalpy of vaporization is the heat required to convert a liquid at its boiling point to vapor.

The Clausius-Clapeyron equation relates the enthalpy of vaporization and vapor pressure.

The expression for Clausius-Clapeyron Equation is shown below as:

  • lnP = ΔHvap/RT + c

Where,

  • P is the vapor pressure
  • ΔHvap is the Enthalpy of Vaporization
  • R is molar gas constant (8.314×10⁻³ kJ /mol K)
  • c is the constant.

Slope of the graph of ln P and 1/T = - ΔHvap/ R

Given that the Slope = -3.46×10³ K

Then,

- ΔHvap/ R = -3.46×10³ K

ΔHvap = 3.46×10³ K × 8.314×10⁻³ kJ /mol K

ΔHvap = 28.7664 kJ /mol

Therefore, the enthalpy of vaporization of the substance.is 28.7664 kJ /mol.

Learn more about enthalpy of vaporization at: https://brainly.com/question/21504082